Climate-Chemical Interactions and Effects of Changing Atmospheric Trace Gases

The problem concerning the greenhouse effects of human activities has broadened in scope frbm the CO2-climate problem to the trace gas-climate problem. The climate ffects of non-CO 2 trace gases are strongly governed by interactions between chemistry, radiation, and dynamics. We discuss in delfiil the natuie of the trace gas radiative heating and describe the importance of radiative-chemical interactions within the troposphere and the stratosphere. We make an assessment of the trace gas effects on troposphere-stratosphere temperature trends for the period covering the preindustrial era to the present and for the next several decades. Non-CO 2 greenhouse gases in the atmosphere are now adding to the greenhouse ffect by an amount comparable to the effect of CO 2. The rate of decadal increase of the total greenhouse forcing is now 3-6 times greater than the mean rate for th• period 1850-1960. Timedependent calculations with a simplified one-dimensional diffusive ocean model suggest that a surface warming about 0.4-0.8 K should have occurred during 1850 to 1980. For the various trace gas scenarios considered in this study, the equilibrium surface warming for the period 1980 to 2030 ranges from 0.8 to 4.1 K. This wide range in the projected warming is due to the range in the assumed scenario as well as due to the threefold uncertainty in the sensitivity of climate models. For the 180-year period from 1850 to 2030, our analysis uggests a trace gas-induced cumulative quilibrium surface warming in the ronge of 1.5 to 6.1 K. The important non-CO 2 greenhouse gases are CFC13, CF2C12, CH 4, N20 , 03, and stratospheric HiO. Chlorofluorocarbons (CFCs)(mainly CFC13. and CF2C12), through their indirect chemical effects on 03, have a potentially large stratospheric cooling effect, as large as that-due to a •20 2 increase. In addition to the direct radiative effect, many of the trace gases have indirect effects on climate. For example, addition of gases uch as CH4, CO, and NO x can alter tropospheric 03, which is a radiatively fictive gas. Within the troposphere the indirect climate effects.can be as large as the direci effects. On the other hand, within the stratosphere, temperature changes are largely determined by indirect effects of CFCs. Trace gases can also influence stratospheric H20 through' their effect on trop!cal tropppause temperatures. Furthe{more, increases in.tropospheric H20 , through the temperature-H20 feedback, can perturb tropospheric hemistry and alter the concentration of CH• and 0 3. The fundamerital issue that needs to be addressed within the context of the trace gas-climate problem is the relative importance of transport, chemistry, and the ihdirect effects of trace gases in governing the long-term trends of tropospheric and stratospheric 03, cH•, and stratospheric H20. Cloud feedback continues to be the major source of uncertainty in the surface temperature sensitivity of climate models. At present, the sign of this feedback is not known. The ocean sequesters the trace gas radiative heating into it• interior and thus delays the equilibrium wai'ming. The estimated e-folding time for the approach to equilibrium varies from a few decades to a century and depends nonlinearly on it-x and linearly on •: where it is the climate feedback parameter and •: is the effective ocean thermal diffusivity. Th• magnitude of it, which also governs the equilibrium surface warming, is governed strongly by radiative and dynaniical processes in the atmosphere, and hence the effect of oceans on transient climate change is determined by the interactions between atmospheric and oceanic dynamical as well as radiative processes. The next crucial issue concerns accurate determination of decadal trends in radiative forcings, trace gases, planetary albedo (to determine effects of aerosols and cloud feedback), and surface-troposphere-stratosphere temperatures. The observational challenges are formidable and must be overcome for a scientifically credible interpretation of the human impacts on climate.